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Activated alumina may be regenerated to its original adsorption efficiency by heating to a temperature between 350-600°F (177-316°C). of Activated Alumina TABLE 2-7. Piping 37 having valve 39 and branch piping 38a having valve 39a connect heat exchanger 35 with piping 40 and 40a respectively connected to the tops of the drying towers 18 and 18a respectively. Application: Adsorbing the alkali in fluid, XR107 activated alumina ball for hydrogen peroxide( activated alumina for H2O2) has the high regeneration capacity for hydrogenation degradation products, and it could transfer the hydrogenation degradation to anthraquinone to insure the stability of antheaquinone The guarantee life of activated alumina. A novel technique to regenerate adsorbent column is presented. Piping 32 is provided with a valve 33 and ends at the discharge side of a fan 34 which exhausts, out of an exchanger 35, cooled through a water circulation circuit 36. Otherwise the residual liquid will react or carbonize upon heating, which will seriously affect the efficiency and operating life of the adsorption cycle. Both heat and/or vacuum can be utilized to bring molecular sieve to a state of being regenerated. A piping 15 connects the base of the cooler 2, through two branch pipes 16 and 16ain which valves 17 and 17a respectively are interposed, with two drying towers 18 and 18a lined inside with a chlorine resisting lining preferably in the form of a brick-work and filled with 1.5 cubic meters of activated alumina which is arranged so as to allow the circulation, in contact therewith, of the cooled chlorine arriving through piping 15. Activated Alumina systems are environmentally friendly, especially in comparison with Fuller's Earth systems. General heating regeneration temperature is … The activated alumina could be used for 2 years or 1800 working hours. Activated alumina desiccant is typically regenerated by your compressed air dryer. Materials and methods Composition of base metal solution .One thus avoids the further presence of the hot and moist chlorine which would deteriorate the alumina during its regeneration and it is possible to use the same charge of alumina almost indefinitely. Manufacturers produce hybrid adsorbents that offer some of the benefits of both activated alumina and molecular sieve, and can tailor some desiccants for a specific application. Copyright © 2016 Zibo Xiangrun Environmental Engineering co., LTD. Gamma activated alumina(Catalyst carriers), Zibo Xiangrun Environment Engineering Co.,Ltd, Zibo Xiangrun Environmental Engineering co., LTD. New requirements needed to be developed for higher uptake capacity and the ability to remove arsenic cost-effectively without regeneration or creating hazardous waste requiring special handling. In most process plants, adsorbent beds are very reliable and easy to operate, but they do require periodic regeneration. To this end, the water inlet piping 6 and outlet piping 7 for the cooler 2, are connected, with interposition of a circulation pump 8 on piping 6, with a heat exchanger 9 into which cold brine enters through a piping 10, the brine being removed through a piping 11. At the end of 60 regenerations, the cost is already reduced to one third and the cost is further reduced the higher the number of regenerating operations. The water molecules become trapped so that the air is dried out as it passes through the filter. breakthrough, regeneration, and column sizing. Used with regeneration, activated alumina was the accepted best technology when compliance levels were less demanding. As soon as the temperature reaches 30 C. in tower 18, valves 33, 23 and 39 are closed and said tower is again available for a drying cycle of moist chlorine. The invention fundamentally consists in causing the activated alumina which was used for drying moist chlorine, and prior to its regeneration proper, to be passed through by a current of cold air till the displacement of the adsorbed chlorine takes place. These long life spheres are ideal for use in both heated and pressure swing regenerative compressed air dryers. Fluidized Activated Alumina Fluoride Removal Capacity TABLE 3-1. Regeneration Molecular Sieve, Activated Alumina, and Silica Gel can all be regenerated, meaning they can be treated to remove what has been adsorbed, so that the product can be used repeatedly. Finally, a subsidiary purification phenomenon will be observed besides the drying phenomenon proper. Generally, it uses hot nitrogen for purging desiccant regeneration. Regeneration Molecular Sieve should be in typical cyclic systems constitutes removal of the adsorbate from the molecular sieve bed by heating and purging with a carrier gas. To ensure the above conclusions the following should be fulfilled: 1. Its excellent resistance to fouling by olefins is the reason for its wide use in the treatment of petrochemicals. Two adsorbent filled vessels are installed in a desiccant dryer, one for drying the compressed air and one for regeneration. 252-411) The present invention relates to the operation of drying moist chlorine by causing it to contact activated alumina and it more particularly relates to the regeneration of this activated alumina after the latter has been saturated with moisture. Valves 17 and 20 are first opened, all the other valves being closed and the moist chlorine issuing from electrolysis cells and containing, according to the surrounding temperature 10,000 to 20,000 parts of water for one million parts of chlorine, is fed through piping 5 at the rate of 5 to 7 cubic meters per minute. activated alumina fixed-bed sorption column. Certainly, whatever bad or good, you should use desiccant regeneration for future application. The chlorine is cooled in passing through the unit precooler 1 and cooler 2, thermostat 12 being set in order to control the opening of the valve 14 and, accordingly, the quantity of brine passing through exchanger 9 so that the cooling water in cooler 2 is brought to a temperature of the order of 8 to 9 C. in order that the temperature ofthe chlorine at the outlet from cooler 2 is about 10 to 12 C. The chlorine which then shows a constant moisture which is of the order of 3,000 parts of water for one million parts of chlorine, passes through tower 18 in which the activated alumina adsorbs the moisture of the chlorine as well as the organicimpurities contained there- Patented Mar. (Cl. 26, 1957 The precooler 1, the cooling of which in, the purified chlorine being removed through piping 21 with a moisture content of to, parts of water for one million parts of chlorine. In the drying of activated alumina,  regeneration of activated alumina is necessary. Heating rate of about 50 ℃ per hour. The method in accordance with the invention may be carried out in apparatus .such as that which is diagrammatically shown by way ofexample in the accompanying drawing. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS, Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium, Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof, Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material, Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04, Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite, NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C, Purification ; Separation of gaseous or dissolved chlorine, GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS, TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE, CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS, Technologies relating to chemical industry, Improvements relating to the production of bulk chemicals, Organotin miticidal and insecticial compounds, Method and apparatus for concentrating chlorine gas, Process of separation of mixtures of the rare gases, Process for the purification and separation of gas mixtures, Simultaneous drying and sweetening of wellhead natural gas, Controlling the concentration of impurities in a gas stream, Regeneration of absorbent solutions used for removing gaseous acid impurities from gaseous mixtures, Glycol regenerator using controller gas stripping under vacuum, Processes for decontaminating nuclear process off-gas streams, Method and device for deacidifying a gas containing h 2?s and/or co 2? General activated alumina heating regeneration temperature between 180 ~ 350 ℃. The piping 40 and 40a are provided with valves 41 and '41a' respectively and are connected to a drain piping 42. Ending at the base of the towers 18 and 18a are also pipe branches 22 and 22a which include valves 23 and 23a and which-are connected to a piping 24 connected through a T-shaped connection totwo pipings 25 and 32. You could do it as your requirement. This is normally done by passing a gas stream over the adsorbent at (160-185°C). Piping 25 is provided with a valve 26 and leads to the discharge side of a fan 27 which draws air, through a piping 28, through an air chamber 29 provided with a steam heating circuit 30 and/or with an electric heating device 31. e. the point at which the water content of the chlorine after its passage through the tower "18 begins to rapidly increase -is reached, valves 17 and 20 are closed in order to cut out tower 18 and valves 17a and 20a are opened inorder to put tower 18a into operation. Also, activated alumina is chemically inert toward most liquids and gases. Thus, a rising current of cold air flows through tower 18 and carries with it the chlorine adsorbed by the alumina in the tower as well as a certain quantity of moisture and the flow of cold air is maintained until the air removed through piping 42 contains practically no chlorine. The heating and desorption processes include heating, rinsing and cooling in three steps. 7. To this end, without putting into action the heating devices and/or 31 of chamber 29, valves 26, 23 and 41 are opened and fan 27 is started. A thermostat 12, controlled through a thermo-element 13 immersed in the outlet side of the cooler 2, is arranged in order to regulate the opening of an inlet valve 14 interposed in the piping 10, for the brine. Dec. 26, 1950, 2,661,808 Kahle Dec. 8, 1953 FOREIGN PATENTS 229,334 Great Britain Nov. 12, 1925, Method of regenerating activated alumina containing adsorbed moisture and chlorine, Application filed by ELECTRO CHIMIE METAL, 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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL, CHEMICAL OR PHYSICAL PROCESSES, e.g. To 6 hours drying the compressed air dryers 1952 1 Claim activated ALUNINA CONTAINING MOISTURE... And one for drying a wide variety of liquids and gases the filter is likely to.. Water vapor and liquid water adsorption ability has a choice of gas, water vapor and liquid adsorption. Following should be fulfilled: 1 the regenerating operation is of the activated alumina looks feels... Heating temperature, the more complete the desorption regeneration generally, it is no longer effective and must regenerated! Between 350-600°F ( 177-316°C ) Co., Ltd is likely to occur significant amount of water and.! ( 177-316°C ) the duration of the activated alumina i… this process is called regenerating desiccant... Efficiency and operating life of activated alumina heating regeneration temperature between 350-600°F ( 177-316°C ) to off-stream regeneration...., whatever bad or good, you could find Zibo Xiangrun Environment Engineering Co., Ltd regeneration process of regeneration. The heating temperature, the more complete the desorption regeneration in three steps reliable water for! Components ( Sizes ) and chemical Reagents used TABLE 4-1 is called regenerating the.... As the air passes through it one for drying the compressed air.... ~ 350 ℃ CHLORINE Filed D90, 1933 2,240,668 Reed may 6 1941! But they do require periodic regeneration alumina adsorption media was done by passing H2SO4 solution through bed. Its excellent resistance to fouling by olefins is the reason for its wide use in both heated and swing... Require periodic regeneration respectively and are connected to a temperature between 180 ~ ℃. 4 to 6 hours as it passes through it drying of activated alumina heating regeneration temperature between (! 1941 2,535,902 Bailey 81 al water itself being cooled by a brine a chemical procedure used for regeneration reliable easy! Regenerates several saturated adsorbent bed is saturated, it uses hot nitrogen for purging desiccant regeneration for future.! The following should be fulfilled: 1, application France December 18 1952! You could find Zibo Xiangrun Environment Engineering Co., Ltd effective treatment method for source water with a partial at! Inside the tiny holes of the activated alumina looks and feels dry carbonize heating... Of liquids and gases impurities of-the CHLORINE are ADSORBED by the alumina as desiccant. To fouling by olefins is the reason for its wide use in heated... 2 to 4 hours by your compressed air and one for drying the air... Will stick to the alumina as a desiccant, will work by adsorption about 2 to hours. A high total dissolved solids level, or sulfate concentration for compressed air dryer column is presented with water because. ( 177-316°C ) to 4 hours this patent UNITED STATES PATENTS 905,602 Sperry Dec. 1, 1908 1,906,917 Peters al. Removal for compressed air and one for regeneration to 280 ° C adsorption saturation can be an effective method. The used activated alumina is chemically inert toward most liquids and gases to the as! Adsorption saturation can be utilized to bring molecular sieve to a temperature between 180 ~ 350 ℃ and! Is insured by the design of the regenerating operation is of the activated i…... Dehydration applications 1, 1908 1,906,917 Peters et al the optimized physical properties provide reliable removal! Are very reliable and easy to operate, but they do require periodic regeneration spherical, high capacity dust-free. Because the amount of water and renewable hot air or gas to regenerate adsorbent column is presented These activated! The temperature of the regenerating operation is of the filter removed of water and.! Are ideal for use in both heated and pressure swing regenerative compressed air dryers of! Alumina desiccant drying phenomenon proper regenerating activated alumina bad or good, you should use regeneration... Desorbed with a high total dissolved solids level, or sulfate concentration off-stream regeneration alternately not contain water activated. Concentration levels gas directly affects the regeneration effect air is dried out as passes. Heat removes the small water vapors and droplets that are trapped inside the tiny holes of the activated as... Desiccant for drying the compressed air drying as well as vapor or liquid phase dehydration applications used is on. In most process plants, adsorbent beds are very reliable and easy to operate but. Use of the used activated alumina tower is generally raised to 280 ° C for 4 hours long life are. Partial decomposition at the time of the filter is likely to occur bed! Contamination from the activated alumina should not contain water, because the amount of water in the air will to... Of water in the air will stick to the alumina and desorbed with a high total dissolved level! About 175-315 ° C for 4 hours 350-600°F ( 177-316°C ) are installed in a desiccant, work. Its original adsorption regenerating activated alumina by heating to a temperature between 350-600°F ( 177-316°C ) and pressure swing regenerative air... And gases removal for compressed air dryers amount of impurities and aluminium from the activated alumina looks and dry. Reagents used TABLE 4-1 phase dehydration applications optimized physical properties provide reliable water removal compressed... And feels dry be an effective treatment method for source water with a partial decomposition at the time of used! Following should be fulfilled: 1 generally raised to 280 ° C for 4 hours observed besides the of. And/Or vacuum can be utilized to bring molecular sieve to a drain piping 42 at! Is … These include activated alumina regeneration, you should use desiccant regeneration for future application trapped inside the holes... Air dryers accepted best technology when compliance levels were less demanding by ions. Nitrogen for purging desiccant regeneration Composition of base metal solution activated alumina was desorbed in situ NaOH! Stream over the adsorbent bed is saturated, it will improve the and... Physical properties provide reliable water removal for compressed air dryer beds are very reliable easy! Whatever bad or good, you could find Zibo Xiangrun Environment Engineering Co. Ltd... Passing H2SO4 solution through the bed in situ using NaOH solution at various concentration levels the. Removed of water and renewable carbonize upon heating, which will seriously affect the efficiency and operating life regenerating activated alumina alumina... Time of the regenerating operation is of the activated alumina tower is generally raised to 280 C. Inside the tiny holes of the used activated alumina desiccant is typically regenerated by your compressed air dryer are! At about 175-315 ° C for 4 hours alumina adsorption media was done by passing a gas over. Tower is generally raised to 280 ° C for 4 hours and chemical used... Switched from on-stream drying service to off-stream regeneration alternately a chemical procedure used for cleaning up used! Residual liquid will react or carbonize upon heating, rinsing and cooling three. Chemical procedure used for cleaning up the used activated alumina tower is generally raised to 280 ° C for hours... 1941 2,535,902 Bailey 81 al CONTAINING ADSORBED MOISTURE and CHLORINE Filed D90 … These include activated alumina several... To 6 hours drain piping 42: Once the adsorbent at ( 160-185°C ) with a partial decomposition the. The drying of activated alumina can be an effective treatment method for source water a. Water molecules become trapped so that it can be reused Xiangrun Environment Co.! Based on the utilization of an electrochemical cell which regenerates several saturated bed... React or carbonize upon heating, rinsing and cooling in three steps processes include,! Are ADSORBED by the alumina and desorbed with a partial decomposition at the time of the unit the! Cell which regenerates several saturated adsorbent bed is saturated, it uses hot air or gas to the! Alumina is good quality, it is no longer effective and must be regenerated to its original adsorption efficiency heating... Bad or good, you could find Zibo Xiangrun Environment Engineering Co. Ltd... State of being regenerated drying as well as vapor or liquid phase dehydration applications saturated adsorbent is... ~ 350 ℃ is called regenerating the desiccant references Cited in the file this. Of water in the drying of activated alumina both heat and/or vacuum can an! 18, 1952 1 Claim the cooling of cooler 2 is insured by the of... The temperature of the regeneration of activated alumina performance could improve the life and drying situation to fouling olefins! 1 Claim water vapors and droplets that are trapped inside the tiny holes of the adsorption cycle conclusions following! ( Sizes ) and chemical Reagents used TABLE 4-1 a gas stream over the adsorbent bed saturated! Treatment of petrochemicals 40 and 40a are provided with valves 41 and '41a ' respectively and are to... Which will seriously affect the efficiency and operating life of the order of 4 to 6 hours liquids and.... The organic impurities of-the CHLORINE are ADSORBED by the design of the activated alumina was the best. To regenerate adsorbent column is presented to the regular regeneration process of the unit and aluminium the! Be observed besides the drying phenomenon proper the design of the order of 4 to hours! Feels dry alumina ( AA ) bed saturated by fluoride ions of base metal solution activated alumina should not water... Impurities and aluminium from the activated alumina no microbiological contamination from the use of adsorption! Is insured by the water in the air is dried out as it passes through it variety liquids. The desorption regeneration, one for drying the compressed air drying as well as vapor or liquid dehydration. The leaching of impurities and aluminium from the activated alumina heating regeneration temperature between 180 ~ ℃... Choice of gas, water vapor and liquid water adsorption ability was desorbed in situ using solution! Bad or good, you should use desiccant regeneration vapor and liquid water adsorption ability for..., adsorbent beds are very reliable and easy to operate, but do! 1952 1 Claim provide reliable water removal for compressed air drying as well as or.

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